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Copper fractal growth during recycling from waste printed circuit boards by slurry electrolysis

《环境科学与工程前沿（英文）》 2021年第15卷第6期 doi: 10.1007/s11783-021-1405-7

摘要：

• Copper fractal growth was observed during WPCBs recycling by slurry electrolysis.

关键词： Dendritic copper Fractal growth WPCBs Slurry electrolysis

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Copper recovery from waste printed circuit boards concentrated metal scraps by electrolysis

Xiaonan Liu, Qiuxia Tan, Yungui Li, Zhonghui Xu, Mengjun Chen

《环境科学与工程前沿（英文）》 2017年第11卷第5期 doi: 10.1007/s11783-017-0997-4

摘要： Copper recovery is the core of waste printed circuit boards (WPCBs) treatment. In this study, we proposed a feasible and efficient way to recover copper from WPCBs concentrated metal scraps by direct electrolysis and factors that affect copper recovery rate and purity, mainly CuSO ·5H O concentration, NaCl concentration, H SO concentration and current density, were discussed in detail. The results indicated that copper recovery rate increased first with the increase of CuSO ·5H O NaCl, H SO and current density and then decreased with further increasing these conditions. NaCl, H SO and current density also showed a similar impact on copper purity, which also increased first and then decreased. Copper purity increased with the increase of CuSO ·5H O. When the concentration of CuSO ·5H O, NaCl and H SO was respectively 90, 40 and 118 g/L and current density was 80 mA/cm , copper recovery rate and purity was up to 97.32% and 99.86%, respectively. Thus, electrolysis proposes a feasible and prospective approach for waste printed circuit boards recycle, even for e-waste, though more researches are needed for industrial application.

关键词： Waste printed circuit boards (WPCBs) Copper Recovery rate Purity Electrolysis